If there are applications or commands that you run every single time you start your computer (Email comes to mind) you may want to consider setting things up so that these programs run automatically during the Windows XP startup. This can be done quite easily in XP by creating shortcuts and shuffling them around.
Here's how: Windows XP has a startup folder located at 'C:\ Documents and Settings\ (your user name)\ Start Menu\ Programs\Startup.' Shortcuts placed into this folder will be run automatically when Windows XP starts up.
If you already have shortcuts for the programs you desire to use, copy and paste them into the startup folder. Otherwise, go to 'start\programs,' select the program you would like to create a shortcut for, right click it and select 'send to' then 'desktop.' This will create a shortcut on the desktop that you can then use.